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Bis(2,4,5-trichlorophenyl-6-carbopentoxyphenyl)oxalate
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Bis(2,4,5-trichlorophenyl-6-carbopentoxyphenyl)oxalate (CPPO) is a solid ester whose oxidation products are responsible for the chemiluminescence in a glowstick. It can be synthesized by reacting 2-carbopentoxy-3,5,6-trichlorophenol with oxalyl chloride.

When mixed with hydrogen peroxide in an organic solvent in the presence of a fluorescent dye CPPO causes the emission of light. The reaction rate is pH dependent, and slightly alkaline conditions achieved by adding a weak base, e.g. sodium salicylate, will produce brighter light. Developed by American Cyanamid in the 1960's, the formulation containing CPPO, a fluorescor, and a glass capsule containing hydrogen peroxide and a base catalyst, all in dialkyl phthalate solvents, was marketed as Cyalume.
The following colors can be produced by using different dyes:
| Color |
Compound |
| Blue |
9,10-Diphenylanthracene |
| Green |
9,10-Bis(phenylethynyl)anthracene |
| Yellow-green |
Tetracene |
| Yellow |
1-Chloro-9,10-bis(phenylethynyl)anthracene |
| Orange |
5,12-Bis(phenylethynyl)naphthacene, Rubrene, Rhodamine 6G |
| Red |
2,4-di-tert-butylph enyl 1,4,5,8-tetracarboxynaphthalene diamide, Rhodamine 101 |
References
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